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Utilization of industrial waste materials. Part 14.† Synthesis of β-amino alcohols and thiols with a 2-azabicyclo[3.3.0]octane backbone and their application in enantioselective catalysis

✍ Scribed by Kossenjans, Michael; Soeberdt, Michael; Wallbaum, Sabine; Harms, Klaus; Martens, Jürgen; Aurich, Hans Günter

Book ID
121707961
Publisher
Royal Society of Chemistry
Year
1999
Weight
316 KB
Volume
16
Category
Article
ISSN
1472-7781

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## Abstract New, chiral β‐__sec__‐amino alcohols 3a–d, 4a–e, and 5a–h have been synthesized from the enantiomerically pure amine (__all‐R__)‐2a. For the diastereo‐ and regioselective α‐hydroxyalkylation of the chiral (__all‐R__)‐__N__‐nitroso‐2‐azabicyclo[3.3.0]octane (__all‐R__)‐2d, Seebach's “one