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Utilisation d'ylides du phosphore non stabilisés en chimie des sucres. V. Sucres ramifiés dérivés du méthyl α-D-lyxo-hexopyrannosul-4-oside. Communication préliminaire

✍ Scribed by J. M. J. Tronchet; J. M. Chalet

Publisher
John Wiley and Sons
Year
1970
Tongue
German
Weight
338 KB
Volume
53
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Cis and trans‐methyl‐4‐deoxy‐2, 3‐O‐isopropylidene‐6‐O‐methyl‐4‐methylthio‐methylene‐α‐D‐lyxo‐hexopyra‐nosides are prepared by a Wittig reaction. Methods are described for the determination of the configuration of the geometrical isomers whose Raney‐Nickel reduction leads to derivatives of 4‐deoxy‐4‐methyl‐hexoses of the D‐manno and D‐talo series.

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