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Utilisation de la guanidine comme agent désacétylant sélectif:une méthode de désacétylation instantanée applicable aux sucres

✍ Scribed by Nicole Kunesch; Christine Miet; Jacques Poisson


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
262 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis


Guunidine efficiently and instantly deprotects a series of acetylated

carbohydrates and phenols at room temperature. Phenolic acetates can be cleaved in the presence of benzylic acetates, while acetamides, benzoates andpivaloates remain stable.