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Using Valence Bond Theory to Understand Electronic Excited States: Application to the Hidden Excited State (2 1 A g ) of C 2 n H 2 n +2 ( n = 2−14) Polyenes

✍ Scribed by Wu, Wei; Danovich, David; Shurki, Avital; Shaik, Sason


Book ID
127194832
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
226 KB
Volume
104
Category
Article
ISSN
1089-5639

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Application of RRKM theory to the reacti
✍ G. P. Smith; D. M. Golden 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 647 KB

## Abstract Rate constants as a function of both temperature and pressure were calculated for the title reactions using RRKM theory in conjunction with a modified Gorin transition state. The modification introduces a hindrance parameter which accounts for repulsive interactions between the rotating