✦ LIBER ✦
Using the comparison of steric versus electronic effects to infer mechanistic information in stepwise electrophilic addition reactions involving three-membered cyclic intermediates
✍ Scribed by Donna J. Nelson; Raman Soundararajan
- Book ID
- 104217748
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- French
- Weight
- 243 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Correlations of 1% versus relative reactivities or formation constants of reactions of alkenes with ArSCl, MeCOSH. Ag+, or HgC12 reveal that complexation reactions show steric dependence, that additions with the first step rate-determining are sterically independent, and that those with the second step rate-determining are sterically dependent.
We recently reported a method of ascertaining the relative importance of steric and