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Using Molecular Symmetry to Form New Drugs: Hydroxymethyl-Substituted 3,9-Diazatetraasteranes as the First Class of Symmetric MDR Modulators

✍ Scribed by Andreas Hilgeroth; Jósef Molnár; Eric De Clercq


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
79 KB
Volume
41
Category
Article
ISSN
0044-8249

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✦ Synopsis


Scheme 1. Synthesis of the monomeric 4-aryl-1,4-dihydropyridines. a) CuI (5 mol %), ROCOCl (1 equiv), 10 min, À8 8C, THF; b) PhMgCl (1 equiv), 30 min, RT, 1 a (75 %), 1 b (83 %); c) tBuOK (2 equiv), 30 min, À18 8C, THF, 1 c (69 %).