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Using barium ions for heavy-atom derivatization and phasing of xylanase II from Trichoderma longibrachiatum

✍ Scribed by Moiseeva, Natalia ;Allaire, Marc


Book ID
104478345
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
468 KB
Volume
63
Category
Article
ISSN
0907-4449

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✦ Synopsis


This paper describes the use of barium chloride to produce a heavy-atom derivative of xylanase II crystals from Trichoderma longibrachiatum, which was obtained either by cocrystallization or soaking. SAD phasing led to interpretable electron-density maps that allowed unambiguous chain tracing. In the best case, with a data set collected at 9.5 keV, 88% of the residues were built, with 83% of the side chains assigned. The barium ions are found to mainly interact with main-chain carbonyl groups and water molecules. It is suggested that barium ions could also be used as a potential anomalous scatterer in the quick cryosoaking procedure for phasing.