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Use of Transient EPR Spectroscopy of Excited Triplet State for the Structural Assignment of Bisadducts of Fullerene C 60

โœ Scribed by Pasimeni, Luigi; Hirsch, Andreas; Lamparth, Iris; Herzog, Andrea; Maggini, Michele; Prato, Maurizio; Corvaja, Carlo; Scorrano, Gianfranco


Book ID
121485466
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
174 KB
Volume
119
Category
Article
ISSN
0002-7863

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Pulsed EPR on the photoexcited triplet s
โœ M. Bennati; A. Grupp; M. Mehring; K.P. Dinse; J. Fink ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 384 KB

We report on the observation of two different triplet states in photoexcited C, fullerene molecules. The following fine structure parameters were determined from spectral fits to the triplet powder spectrum: IDI [=0.0117 cm-' (12.5 mT), lJ&l=O.O014 cm-' (1.5 mT) and / D2j ~0.0047 cm-' (5 mT), l&l =O