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Use of the N-oxide of p-cyano-N,N-dimethylaniline as an "oxygen" donor in a cytochrome P-450 model system

✍ Scribed by Nee, Michael W.; Bruice, Thomas C.


Book ID
126249109
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
399 KB
Volume
104
Category
Article
ISSN
0002-7863

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The photoreduction behavior of p-nitroaniline (pNA) in the presence of N,N-dimethylaniline (DMA) induced by both steady-state (365 nm) and laser (337 nm) irradiation has been analyzed. The stoichiometry of the photoreduction reaction revealed that several amino radicals derived from DMA were generat