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Use of the Eu(fod)3-Induced Shift for Determination of the Complexation Site and for Signal Assignment in the 13C-NMR Spectra of Protected Dipeptides

✍ Scribed by Prof. Dr. Horst Kessler; Dipl.-Chem. Michael Molter


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
220 KB
Volume
13
Category
Article
ISSN
0044-8249

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The role of ?-type nonbonding orbitals f
✍ Kaupp, Martin; Malkina, Olga L.; Malkin, Vladimir G. πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 246 KB πŸ‘ 2 views

type nonbonding orbitals on heavy halogen or related substituents are largely responsible for significantly shielding spin᎐orbit-induced Ž . heavy-atom effects on nuclear magnetic resonance NMR chemical shifts of the neighboring atoms. This suggestion has been examined and confirmed by Ž . 13 densi