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Use of the Brönsted Equation in the Interpretation of Micellar Effects in Kinetics (II). Study of the Reaction [Fe(CN) 5 (4-CNpy)] 3- + CN - ⇄ Fe(CN) 64- + 4-CNpy in CTACl Micellar Solutions

✍ Scribed by Muriel-Delgado, Fernando; Jiménez, Rafael; Gómez-Herrera, Carlos; Sánchez, Francisco


Book ID
127107501
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
71 KB
Volume
15
Category
Article
ISSN
0743-7463

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📜 SIMILAR VOLUMES


Study of the reaction Fe(CN)5(4-CNpy)3−
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The reaction (4-CNpy ϭ 4-cyanopyridine) was studied 3Ϫ 2Ϫ Fe(CN) (4-CNpy) ϩ S O 5 2 8 in aqueous salt solutions in the presence of several electrolytes as well as in anionic, cationic, and nonionic surfactant solutions. In aqueous salt solutions the noncoulombic interactions seem to be important in

Study of the Reaction Fe(CN)5(4-CNpy)3-
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The ligand substitution process \(\mathrm{Fe}(\mathrm{CN})_{5}(4-\mathrm{CNpy})^{3-}+\mathrm{CN}^{-}\) (4-CNpy is 4-cyanopyridine) has been studied in various AOT (sodium bis(2-ethylhexyl) sulphosuccinate)-oil-water microemulsions at \(298.2 \mathrm{~K}\) (oil = heptane, octane, iso-octane, nonane,

Study of the reaction Fe(CN)4(bpy)2− + S
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## Abstract The reaction Fe(CN)~4~(bpy)^2−^ + S~2~O~8~^2−^ has been studied in aqueous micellar solutions of __N__‐tetradecyl‐__N,N__‐dimethyl‐3‐ammonio‐1‐propanesulfonate, SB3‐14. The influence of changes in the surfactant concentration as well as in the peroxodisulfate ions concentration on __k__

Study of the ligand substitution reactio
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The ligand substitution reaction Fe(CN) 5 H 2 O 3Ϫ ϩ pyrazine : Fe(CN) 5 pyrazine 3Ϫ ϩ H 2 O has been studied in sodium dodecyl sulfate, SDS, hexadecyltrimethylammonium bromide, CTAB, and salt aqueous solutions at 298.2 K. Kinetics were studied in dilute and concentrated salt solutions and in SDS an

Micellar effects on a ligand substitutio
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## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i