The reaction (4-CNpy ϭ 4-cyanopyridine) was studied 3Ϫ 2Ϫ Fe(CN) (4-CNpy) ϩ S O 5 2 8 in aqueous salt solutions in the presence of several electrolytes as well as in anionic, cationic, and nonionic surfactant solutions. In aqueous salt solutions the noncoulombic interactions seem to be important in
Use of the Brönsted Equation in the Interpretation of Micellar Effects in Kinetics (II). Study of the Reaction [Fe(CN) 5 (4-CNpy)] 3- + CN - ⇄ Fe(CN) 64- + 4-CNpy in CTACl Micellar Solutions
✍ Scribed by Muriel-Delgado, Fernando; Jiménez, Rafael; Gómez-Herrera, Carlos; Sánchez, Francisco
- Book ID
- 127107501
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 71 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0743-7463
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📜 SIMILAR VOLUMES
The ligand substitution process \(\mathrm{Fe}(\mathrm{CN})_{5}(4-\mathrm{CNpy})^{3-}+\mathrm{CN}^{-}\) (4-CNpy is 4-cyanopyridine) has been studied in various AOT (sodium bis(2-ethylhexyl) sulphosuccinate)-oil-water microemulsions at \(298.2 \mathrm{~K}\) (oil = heptane, octane, iso-octane, nonane,
## Abstract The reaction Fe(CN)~4~(bpy)^2−^ + S~2~O~8~^2−^ has been studied in aqueous micellar solutions of __N__‐tetradecyl‐__N,N__‐dimethyl‐3‐ammonio‐1‐propanesulfonate, SB3‐14. The influence of changes in the surfactant concentration as well as in the peroxodisulfate ions concentration on __k__
The ligand substitution reaction Fe(CN) 5 H 2 O 3Ϫ ϩ pyrazine : Fe(CN) 5 pyrazine 3Ϫ ϩ H 2 O has been studied in sodium dodecyl sulfate, SDS, hexadecyltrimethylammonium bromide, CTAB, and salt aqueous solutions at 298.2 K. Kinetics were studied in dilute and concentrated salt solutions and in SDS an
## Abstract The kinetics of substitution of H~2~O by Ru(NH~3~)~5~pz^2+^ (pz = pyrazine) in Fe(CN)~5~H~2~O^3−^ have been studied in micellar aqueous solutions of sodium dodecylsulfate (SDS). Experimental results are discussed by using an approach based on the transition‐state theory. This approach i