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Use of Selective Deuteration and 1H NMR in Demonstrating Major Groove Binding of .DELTA.-[Ru(phen)2dppz]2+ to d(GTCGAC)2

✍ Scribed by Dupureur, Cynthia M.; Barton, Jacqueline K.


Book ID
126439585
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
233 KB
Volume
116
Category
Article
ISSN
0002-7863

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## Abstract We present the application of a 2D broadband homodecoupled proton NMR experiment to the visualization of enantiomers. In a chiral environment, the existence of diastereoisomeric intermolecular interactions can yield—generally slight—variations of proton chemical shifts from one enantiom