Use of Precipitons for Copper Removal in Atom Transfer Radical Polymerization
โ Scribed by Honigfort, Mical E.; Brittain, William J.; Bosanac, Todd; Wilcox, Craig S.
- Book ID
- 127106731
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 42 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0024-9297
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๐ SIMILAR VOLUMES
## Abstract **Summary:** We describe the removal of copper from atom transfer radical polymerization (ATRP) through electrochemistry. __tert__โButyl methacrylate ATRP initiated by a PEO macroinitiator was run with CuBr complexed by __N__โalkylโ2โpyridylmethanimine (Schiff base) or 2,2โฒโbipyridyl (b
## Abstract A simple method has been described to remove catalyst from the copper mediated atom transfer radical polymerization (ATRP) of benzyl methacrylate and methyl methacrylate in anisole at 25โยฐC using hydrated natural clay (sodium montmorillonite, Naโclay). The method consists of (1) additio