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Use of Methyl Iodide for Probing the Polarity of the Immediate Environment of—SH Groups in Thiolenzymes : Reaction of Methyl Iodide with Thiolsubtilisin

✍ Scribed by Piroska HALÁSZ; László POLGÁR


Book ID
115115785
Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
641 KB
Volume
71
Category
Article
ISSN
1432-1327

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Kinetics and rate constants for the reac
✍ D. J. Carlsson; K. U. Ingold; L. C. Bray 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

The kinetics of the photoinitiated reductions of methyl iodide and carbon tetrachloride by tri-n-butylgermanium hydride in cyclohexane at 25°C have been studied and absolute rate constants have been measured. Rate constants for the combination of CH,. and CC1,. radicals are equal within experimental