𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Use of mercuric resins for selective abstraction of mercaptans in capillary gas chromatography

✍ Scribed by Sun, Jeffrey J. ;Fritz, James S.


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
307 KB
Volume
15
Category
Article
ISSN
0935-6304

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

A small amount of mercuric non‐porous resin placed in the liner of the injection splitter of a gas chromatograph retains mercaptans but allows other organic sulfur and non‐sulfur compounds to be chromatographed normally: mercaptans in the gaseous state are retained by the mercuric resin. The method works well at 200Β°C but an increasing number of impurity peaks are observed as the temperature is increased to 250Β°C.


πŸ“œ SIMILAR VOLUMES


Abstraction of basic compounds by sulfon
✍ Sun, Jeffrey J. ;Fritz, James S. πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 407 KB

## Abstract A small amount of a lightly sulfonated non‐porous resin placed in the liner of the injection splitter of a gas chromatograph retains basic organic compounds but allows neutral compounds to be chromatographed normally. The organic bases in the gaseous state react with sulfonic acid group

The use of precolumns for solvent focusi
✍ Yan, Zimeng ;Nikelly, John G. πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 443 KB πŸ‘ 1 views

## Abstract In trace analysis by capillary GC it is often desirable to use larger than normal injection volumes to obtain sufficient sensitivity. This, however, results in a wider solvent peak and tailing, and may reduce column efficiency. This paper describes the use of a short length of a capilla

Evaluation of a radio frequency plasma f
✍ Pedersen-Bjergaard, Stig ;Greibrokk, Tyge πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 448 KB πŸ‘ 1 views

## Abstract A radio frequency plasma detector for capillary GC has been modified for oxygen‐selective detection. Purification of the plasma gas and purging of both ends of the discharge region with helium were crucial to minimizing oxygen background emission from impurities in the plasma. With a pu