✦ LIBER ✦

Use of ion-molecule reaction equilibria to identify structural isomers

✍ Scribed by Robert T. McIver Jr

Book ID: 102557865
Publisher: John Wiley and Sons
Year: 1975
Tongue: English
Weight: 218 KB
Volume: 10
Category: Article
ISSN: 1076-5174
DOI: 10.1002/oms.1210100511

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✦ Synopsis

Abstract

A new approach is described for identifying structural isomers which cannot be distin‐guished on the basis of their electron‐impact mass spectra. Using a pulsed ion cyclotron resonance mass spectrometer, equilibrium constsnts are measured for ion‐molecule reactions involving various C~8~H~10~ isomers and C~7~H~8~O isomers. The equilibrium constants are shown to be highly sensitive to the structural features of the various isomers.

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