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Use of Infrared Multiphoton Photodissociation with SWIFT for Electrospray Ionization and Laser Desorption Applications in a Quadrupole Ion Trap Mass Spectrometer

✍ Scribed by Colorado, Armando; Shen, Jim Xiangxin; Vartanian, Victor H.; Brodbelt, Jennifer


Book ID
126965480
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
885 KB
Volume
68
Category
Article
ISSN
0003-2700

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In this work we demonstrate the use of peptide as a stable internal mass standard to obtain accurate mass measurements of infrared multiphoton dissociation (IRMPD) generated phosphorothioate oligonucleotide fragment ions. Because oligonucleotides are more readily dissociated in the gas phase by IRMP