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Use of hybrid organic-siliceous catalysts for the selective conversion of glycerol

✍ Scribed by François Jérôme; Joël Barrault

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
482 KB
Volume
113
Category
Article
ISSN
1438-7697

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## Abstract The unprecedented ability of neodymium‐based metal organic frameworks (MOFs) as polymerisation pre‐catalysts towards isoprene is reported. Combined with methylaluminoxane (MAO) or modified MAO (MMAO), they afford mainly __cis__‐selective polyisoprene, up to 90.7%. Both the activity and