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Use of Heterogeneous Catalyst KG-60-NEt2 in Michael and Henry Reactions Involving Nitroalkanes.

✍ Scribed by Roberto Ballini; Giovanna Bosica; Damiana Livi; Alessandro Palmieri; Raimondo Maggi; Giovanni Sartori

Publisher: John Wiley and Sons
Year: 2003
Weight: 15 KB
Volume: 34
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200324037

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Abstract

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Use of heterogeneous catalyst KG-60-NEt2

Use of heterogeneous catalyst KG-60-NEt2 in Michael and Henry reactions involving nitroalkanes

✍ Roberto Ballini; Giovanna Bosica; Damiana Livi; Alessandro Palmieri; Raimondo Ma 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 101 KB

The N,N-diethylpropylamine supported on amorphous silica (KG-60-NEt 2 ) catalyses the formation of carbon carbon bonds by nitroalkanes through both the nitroaldol (Henry) and Michael reactions. The catalyst shows general utility with a variety of electrophilic acceptors. Moreover, the catalyst can b