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Use of Gas-Phase 1 H NMR to Determine the Kinetics of Unimolecular Rearrangement of 2,2-Dichloro-1-methylenecyclopropane and the Bimolecular Dimerization of (Dichloromethylene)cyclopropane †

✍ Scribed by Shtarov, Alexander B.; Krusic, Paul J.; Smart, Bruce E.; Dolbier, William R.

Book ID
127286352
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
60 KB
Volume
67
Category
Article
ISSN
0022-3263

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Kinetics of the reactions of cyclopropan
Kinetics of the reactions of cyclopropane derivatives. V. The gas-phase unimolecular reactions of 1 α-chloro-2α,3α-dimethylcyclopropane and 1α-chloro-2α,3β-dimethylcyclopropane
✍ P. J. Robinson; M. J. Waller 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 622 KB

## Abstract Thermolysis of the “all‐__cis__” compound 1α‐chloro‐2α,3α‐dimethylcyclopropane (A) at 550–607 K and 6–115 torr is a first‐order homogeneous non‐radical‐chain process giving penta‐1,3‐diene (PD) and HCl as products. The Arrhenius parameters are log~10~__A__(sec^−1^) = 13.92 ± 0.08 and __