𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Use of Fluorine Kinetic Isotope Effects in the Study of Steric Effects in Nucleophilic Aromatic Substitution Reactions

✍ Scribed by Persson, Jonas; Matsson, Olle

Book ID
127014595
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
31 KB
Volume
63
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Kinetic solvent isotope effect for aroma
Kinetic solvent isotope effect for aromatic nucleophilic substitution in mixtures of EtOH and EtOD
✍ M. G. Cattania; P. Beltrame πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 274 KB

## Abstract Rate coefficients for the ethoxydechlorination of 1‐chloro‐2,4‐dinitrobenzene were measured in mixtures of EtOH and EtOD of different deuterium atom fraction __n__ (__n__ = 0., 0.259, 0.377, 0.581, 0.767, 0.958), at 25Β°C. The extreme solvent isotope effect, obtained by different extrapo

The influence of some steric and electro
The influence of some steric and electron effects on the mechanism of aromatic nucleophilic substitution (SNAr) reactions in nonpolar solvent
✍ Thomas A. Emokpae; Nkechi V. Atasie πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 90 KB πŸ‘ 1 views

## Abstract Kinetic studies are reported for the reactions with aniline in benzene of a series of X‐phenyl 2,4,6‐trinitrophenyl ethers [X = H; 2‐, 3‐, 4‐CH~3~; 2,4‐, or 2,6‐(CH~3~)~2~] a–f, and the results compared with those of the corresponding nitro derivatives. In the methyl series, kinetic dat