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Use of chloramine-T selective electrode in the kinetic microdetermination of iodide by means of its catalytic effect on the chloramine-T?hydrogen peroxide reaction

✍ Scribed by Koupparis, M. A. ;Hadjiioannou, T. P.


Publisher
Springer-Verlag
Year
1978
Weight
285 KB
Volume
70
Category
Article
ISSN
0344-838X

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A catalytic spectrophotometric method for the determination of trace amounts of bromide is proposed. In acidic solution 4,4'-bis(dimethylamino)diphenylmethane (tetrabase) is oxidized by chloramine T to form a blue compound, which is further oxidized to a greenish-yellow compound. The reaction is acc