Use of Biogenetic Key Compounds for the Biomimetic Synthesis of Natural Products: (S)-Elenolide from Secologanin
β Scribed by Prof. Dr. Lutz-F Tietze; Dipl.-Chem. Horst C. Uzar
- Publisher
- John Wiley and Sons
- Year
- 1979
- Tongue
- English
- Weight
- 226 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Natural Products Synthesis by retro-Diels-Alder Reactions. Part 15. Using a Rigid Molecule Tricyclodecadienone for the Stereospecific Synthesis of the Chain Compound Senecivernic Acid. -A highly efficient synthesis of senecivernic acid (XV), a metabolite of the pyrrolizidine alkaloid senecivernine,
5Π-Acetylthio-5Π-deoxy-2Π,3Π-O-isopropylideneadenosine (8) was directly prepared from commercially available 2Π,3Π-Oisopropylideneadenosine ( 7) and thioacetic acid under Mitsunobu conditions in almost quantitative yield. In situ cleavage of the acetylthio function of 8 followed by coupling with dif