𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Use of alumina for elimination of sulfinic acid from β-aryl- and β-alkylsulfonyl carbonyl compounds.

✍ Scribed by Joëlle Vidal; Francois Huet


Book ID
104217982
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
189 KB
Volume
27
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Title compounds give a-unsaturated carbonyl compounds by treatment with basic alumina in dichloromethane or diethylether. Ck'-Enones are thus obtained in high yield at room temperature.


📜 SIMILAR VOLUMES


Enamine oxidations. 2. Selective oxidati
✍ Clifford E. Harris; William Chrisman; Sally A. Bickford; Lawrence Y. Lee; Antoni 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 202 KB

Treatment of fl, fl -disubstituted enamines with potassium permanganste suppocted on neutral alumina leads to a mild and selective oxidative cleavage reaction which produces ketones and formamides. The ketones can be isolated in high yield and purity by a simple workup procedure. The oxidizing agent