## Abstract The free‐radical copolymerization of methyl acrylate with styrene initiated by triphenylstibonium 1,2,3,4‐tetraphenylcyclopentadienylide under nitrogen blanket at (60 ± 0.1)°C in 1,4,dioxane for 2 h has been carried out. The kinetic expression is __R~p~__ ∝ [I]^0.14^ [MA]^0.70^ [Sty]^0.
✦ LIBER ✦
Use of a Novel Tetrafunctional Initiator in the Free Radical Homo‐ and Copolymerization of Styrene, Methyl Methacylate and α‐Methyl Styrene
✍ Scribed by Scorah, M. J.; Dhib, R.; Penlidis, A.
- Book ID
- 127342711
- Publisher
- Taylor and Francis Group
- Year
- 2005
- Tongue
- English
- Weight
- 855 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1060-1325
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## Abstract The free‐radical copolymerization propagation kinetics of the bio‐renewable monomer __γ__‐methyl‐__α__‐methylene‐__γ__‐butyrolactone (MeMBL) with styrene (ST) and with methyl methacrylate (MMA) have been investigated by the pulsed laser polymerization (PLP)—size exclusion chromatography