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Uranyl binding by a novel bis-calix[4]arene receptor

✍ Scribed by Philippe Schmitt; Paul D. Beer; Michael G.B. Drew; Paul D. Sheen


Book ID
104259710
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
163 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new bis-calix[4]arene receptor 3 has been synthesized which complexes and extracts the uranyl cation in organic media.


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Bis(amidopyridine)-linked calix[4]arenes
✍ Hidekazu Miyaji; Miroslav Dudic; James H.R Tucker; Ivan Prokes; Mark E Light; Mi πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 229 KB

Calix[4 ]arenes 1 and 2, functionalised on their upper rim with amidopyridine groups, have been synthesised. In the case of 1, a detailed binding study with a range of aliphatic and aromatic dicarboxylic acids has been carried out using 1 H NMR spectroscopy. The binding affinities are largely depen