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Uranium–Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIVC Bonds

✍ Scribed by Oliver J. Cooper; Dr. David P. Mills; Dr. Jonathan McMaster; Dr. Fabrizio Moro; Dr. E. Stephen Davies; Dr. William Lewis; Prof. Alexander J. Blake; Dr. Stephen T. Liddle

Book ID
101572917
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
363 KB
Volume
50
Category
Article
ISSN
0044-8249

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Uranium–Carbon Multiple Bonding: Facile
Uranium–Carbon Multiple Bonding: Facile Access to the Pentavalent Uranium Carbene [U{C(PPh2NSiMe3)2}(Cl)2(I)] and Comparison of UVC and UIVC Bonds
✍ Oliver J. Cooper; Dr. David P. Mills; Dr. Jonathan McMaster; Dr. Fabrizio Moro; 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 374 KB

Compared to the extensive investigations of d-block metalligand multiple bonding and reactivity, [1] the corresponding field of f-block chemistry is underdeveloped. [2,3] For uranium, imido and oxo complexes dominate, yet there is a paucity of uranium carbenes that do not derive from neutral free ca