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Uranium alkoxide chemistryV. Synthesis, characterization and interconversion of uranium(IV) tert-butoxide complexes

✍ Scribed by William G. Van der Sluys; Alfred P. Sattelberger; Michael W. McElfresh

Book ID
108428736
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
595 KB
Volume
9
Category
Article
ISSN
0277-5387

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✍ Polly L. Arnold; Alexander J. Blake; Claire Wilson 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 123 KB

## Abstract The syntheses of two tetravalent uranium alkoxide‐carbene complexes are reported, [UIL~3~], and [UL~4~] where L=OCMe~2~CH~2~[1‐C(NCHCHN__i__Pr)]. The latter shows dynamic behaviour of the alkoxycarbene ligands in solution at room temperature, and the crystal structure of [UL~4~] shows t