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Ups of thiols and disulfides adsorbed on Cu(410): CH3SH, C2H5SH, C3H7SH, (CH3S)2, (C2H5S)2, (C3H7S)2

✍ Scribed by S.E. Anderson; G.L. Nyberg


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
907 KB
Volume
52
Category
Article
ISSN
0368-2048

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Kinetics and mechanism for the reactions
✍ D. Martin; J. L. Jourdain; G. Le Bras πŸ“‚ Article πŸ“… 1988 πŸ› John Wiley and Sons 🌐 English βš– 462 KB πŸ‘ 1 views

A kinetic study of the reactions of H atoms with CH,SH and C2H6SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 \* 0.20) x lo-'' for the reaction H + CH3SH (1) and k2 = (2.40 t