Kinetics and mechanism for the reactions
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D. Martin; J. L. Jourdain; G. Le Bras
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Article
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1988
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John Wiley and Sons
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English
β 462 KB
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A kinetic study of the reactions of H atoms with CH,SH and C2H6SH has been carried out at 298 K by the discharge flow technique with EPR and mass spectrometric analysis of the species. The pressure was 1 torr. It was found: k1 = (2.20 \* 0.20) x lo-'' for the reaction H + CH3SH (1) and k2 = (2.40 t