✦ LIBER ✦

Upper limit for the rate of reaction of Cl(2PJ) with methyl chloroform

✍ Scribed by P.H. Wine; D.H. Semmes; A.R. Ravishankara

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 351 KB
Volume: 90
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83625-7

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✦ Synopsis

Rccc~vcd 10 hfay 1982 The kmebcs or the rcactlon CI('PJ) + CH~CCI~ kg -6HzCC13 + HCI has been investigated over the tcmpersturr: range X9-403 I; Cl(*P,) was prepacd by 355 nm pulsed laser photolysls of Cl2 and detected by time-resolved rcsonancc tluorcsccncc. Uppcr hmits for kl(7') in umts of lo-l4 cm3 molcculc-l s-l arc 2.40 at 259 K, 3.68 at 298 K, and 7.74 nt 356 K. At 403 K, secondary produrtion oTCI('P,) was obrrved llndcr all expenmcntal conditions. The title rcactlon is too slow to be Important III atmosphcnc chcrms&.

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