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Upon the existence of [Al3Cl10]− in room temperature chloroaluminate ionic liquids

✍ Scribed by Ala'a K. Abdul-Sada; Anthony M. Greenway; Kenneth R. Seddon; Thomas Welton

Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
172 KB
Volume
24
Category
Article
ISSN
1076-5174

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✦ Synopsis

A negative-ion fast-atom-bombardment mass spectrometric study of the room temperature chloroaluminate ionic liquids AIC1,-(MeEtim]Cl (IMeEtimJ' = 1-methyl-3-ethylimidazolium cation) has produced the first unambiguous experimental evidence for the existence of [A13Cl,,,J-.

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A fast atom bombardment mass spectrometr
A fast atom bombardment mass spectrometric study of room-temperature 1-ethyl-3-methylimidazolium chloroaluminate(III) ionic liquids. Evidence for the existence of the decachlorotrialuminate(III) anion
✍ Ala'a K. Abdul-Sada; Anthony M. Greenway; Kenneth R. Seddon; Thomas Welton 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 481 KB

Previous studies of lethyl-3-methylimidazolium chloride-aluminium(II1) chloride (1 emim] Cl-AICI,) ionic liquids have been hampered by significant contamination of these liquids by oxide impurities. Treatment of these liquids with phosgene removes the oxide impurities, and the use of a specially con