Upgraded coal-derived liquids obtained from catalytic hydroprocessing of a 30-70(wt%) blend of SRC-1 with SRC-II have been studied by infrared and proton magnetic resonance spectroscopy, and gel permeation chromatography techniques. Compared with the feed blend, the upgraded liquids exhibit a lower
Upgrading of coal-derived products
โ Scribed by Peter C. Wailes
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 652 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0016-2361
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โฆ Synopsis
A number of processessuch as pyrolysis, solvent extraction, etc. can be used for the primary upgrading of coal to liquid products. The type of process used can have a significant influence on the character of the product obtained. The chemistry and associated problems involved in the catalytic hydrotreatment of flash pyrolysis tars are discussed in this Paper. The difficulties encountered in the upgrading of flash pyrolysis tar are due principally to factors such as the thermal instability of the tar (high Conradson carbon), particulate matter in the tar and the high molecular weight of the tar. The design and mode of operation of the reactor have been chosen to minimize such problems. An important function of the catalyst used in this work (C&MO-AI,O, and Ni-Mo-A1203) was to reduce the heteroatom content of the feedstock. A description of the type of molecules and reactions involved in tar upgrading is given.
๐ SIMILAR VOLUMES
Co-pyrolysis was investigated as a method of upgrading various products resulting from coal processing. Co-pyrolysis of vacuum residue (VR) with coal extraction products as well as with priman/ tarsfromflash pyrolysis leadstoaconsiderablyenhanced yield of liquid products. It has beenestablished that
Upgraded coal-derived liquids obtained from catalytic hydroprocessing of SRC-II and H-coal syncrudes have been studied by i.r., p.m.r., g.c.-m.s., and silica gel chromatography. With increase in residence time, nitrogen, oxygen and aromatics decrease, while naphthenes increase substantially. All the
The mass range and the number-average molecular weight of coal-derived liquids upgraded with various catalysts were determined by field-ionization mass spectrometry (FIMS). The differences in the main components in liquids upgraded with HDS (hydrodesulphurization) and zeolite catalysts were clarifie