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Up-Conversion Photoluminescence in Polyfluorene Doped with Metal(II)–Octaethyl Porphyrins

✍ Scribed by P.E. Keivanidis; S. Baluschev; T. Miteva; G. Nelles; U. Scherf; A. Yasuda; G. Wegner

Book ID: 101411667
Publisher: John Wiley and Sons
Year: 2003
Tongue: English
Weight: 153 KB
Volume: 15
Category: Article
ISSN: 0935-9648
DOI: 10.1002/adma.200305717

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✦ Synopsis

The up‐conversion photoluminescence (PL) in films of polyfluorene (PF) doped with metallated porphyrins is reported for the first time. The dependence of the up‐conversion process on the pump laser intensity and wavelength, the central metal moiety of the dopants, and the temperature is presented. Up‐conversion emission is observed at pump intensities as low as 2 kW cm^–2^. Comparison of the PF integral PL intensities after laser excitation by 532, 543, and 405 nm enables the discussion of the energy‐transfer mechanism and the efficiency of the process.

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