The radical cation of bicyclo[2.2.l]hepta-2,5-diene (8,9,10-trinorboma-2,5-diene; 1) in CF,CICFCl, and CF,CCl, matrices and that of bicyclo[2.2.2]octa-2,5-diene (2,3-dihydrobarrelene; 2) in CFC1, and CF,CCl, matrices have been studied by ESR and'ENDOR spectroscopy. For It, the coupling constants of
✦ LIBER ✦
Unusually Tight Ion Pairing of the 1,4- and 2,3-Di- tert -butylbuta-1,3-diene Radical Anions with Alkali-Metal Cations: An ESR and ENDOR Study
✍ Scribed by Gerson, Fabian; Hopf, Henning; Merstetter, Pascal; Mlynek, Cornelia; Fischer, Dagmar
- Book ID
- 126209876
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 190 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The radical anions and radical cations of two alkyl‐substituted non‐alternant hydrocarbons, 1,3,5,7‐tetra‐__tert__‐butyl‐__s__‐indacene and 2,7‐di‐__tert__‐butyldicyclopenta [__a,e__] cyclooctene, were characterized by their proton coupling constants with the use of ESR and, in part, EN