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Unusual α-aminoacids from vinylglycine

✍ Scribed by P. Meffre; L. Vo-Quang; Y. Vo-Quang; F. Le Goffic

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
215 KB
Volume
31
Category
Article
ISSN
0040-4039

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## Abstract Enantiomerically pure vinylglycine (4b) can be prepared from natural („chiral pool”︁) amino acids by photoelimination of γ‐functionalized __N__‐phthaloyl amino acid esters. Two routes have been developed: (a) a three‐step synthesis of substrate 3b [PhtN‐Met(SO)OMe] from (__S__)‐methioni