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Unusual transformations of methyl β-nitropropionate upon reaction with silylating agents

✍ Scribed by V. M. Danilenko; S. L. Ioffe; Yu. A. Strelenko; N. F. Karpenko; A. V. Kalinin; V. A. Tartakovskii

Book ID
112447064
Publisher
Springer
Year
1987
Tongue
English
Weight
152 KB
Volume
36
Category
Article
ISSN
1573-9171

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The catalytic asymmetric aldol reaction
The catalytic asymmetric aldol reaction of aldehydes with unsubstituted and monosubstituted silyl ketene acetals: formation of anti-β-hydroxy-α-methyl esters
✍ Emma R. Parmee; Yaping Hong; Orin Tempkin; Satoru Masamune 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 272 KB

The title reaction with unsubstifufed and monosubstituted silyf ketene acetals proceeds with high enantioseiectivify, and in the latter case good dinstereoselecfivity favoring the anfi-/Chydrory-amethyl esters in all reported cases.