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Unusual Syntheses, Structures, and Electronic Properties of Compounds Containing Ternary, T3-Type Supertetrahedral M/Sn/S Anions [M5Sn(μ3-S)4 (SnS4)4]10- (M: Zn, Co).

✍ Scribed by Christian Zimmermann; Christopher E. Anson; Florian Weigend; Rodolphe Clerac; Stefanie Dehnen


Publisher
John Wiley and Sons
Year
2005
Weight
18 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis and Structure of [Sn4Se11]6–,
✍ Anja Loose; William S. Sheldrick 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 1 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re