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Unusual structures derived from N-acridin-9-yl methyl N′-acridin-9-yl thiourea based on the propensity of N-10 to retain H

✍ Scribed by Karel D. Klika; Kalevi Pihlaja; Ján Imrich; Mária Vilková; Juraj Bernát


Publisher
Journal of Heterocyclic Chemistry
Year
2006
Tongue
English
Weight
305 KB
Volume
43
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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N‐Acridin‐9‐yl methyl N′‐acridin‐9‐yl thiourea spontaneously spiro cyclises via nucleophilic attack of the methylene carbon onto the C‐9 of the other acridine moiety. The thiourea, upon reaction with bromoacetonitrile, provided a spiro fused‐bicyclic product displaying unusual dynamic behavior.


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Unusual Structure Derived from N-Acridin
✍ Karel D. Klika; Jan Imrich; Maria Vilkova; Juraj Bernat; Kalevi Pihlaja 📂 Article 📅 2006 🏛 John Wiley and Sons ⚖ 16 KB

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