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Unusual Strong Ortho Effects in the Rearrangement of Binuclear Gold(I) Complexes

✍ Scribed by Hermann, Holger L.; Schwerdtfeger, Peter; Mohr, Fabian; Bhargava, Suresh K.


Book ID
126887579
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
111 KB
Volume
22
Category
Article
ISSN
0276-7333

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Treatment of the (isocyanide)gold(I) species LAuCl (L t BuNC, 2,6-Me 2 C 6 H 3 NC) with 4-mercaptobenzoic acid in the presence of NaOMe yields the complexes [Au(4-SC 6 H 4 CO 2 H)L] in good yield. Reaction of LAuCl with 2-HSQn (Qn quinoline) and 2-HSPy (Py pyridine) under the same conditions provide