Unusual stabilization of water-soluble colloidal MnO2during the oxidation of paracetamol by({mathop {MnO_{4} } olimits^ - })
✍ Scribed by Parveen Kumar; Zaheer Khan
- Publisher
- Springer
- Year
- 2006
- Weight
- 168 KB
- Volume
- 284
- Category
- Article
- ISSN
- 0340-255X
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## Abstract Nanocrystalline LiMn~2~O~4~ is synthesized from aqueous solutions of Mn(OAc)~2~, LiNO~3~, citric acid, and urea (calcination at 350 °C for 12 h) and by solid state reaction of a stoichiometric mixture of Li~2~CO~3~ and Mn~2~O~3~ (850 °C, 24 h).
## Abstract The oxidation of 2,4,6‐trichlorophenol (TCP) to 2,6‐dichloro‐1,4‐benzoquinone (DCQ) by hydrogen peroxide using iron(III) meso‐tetra(4‐sulfonatophenyl) porphine chloride, Fe(TPPS)Cl, as a catalyst was studied with stopped‐flow UV–vis spectrophotometry and potentiometry using a chloride i