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Unusual solvent effects in the Wittig reaction of some ketones indicating initial one-electron transfer

✍ Scribed by Olah, George A.; Krishnamurthy, V. V.


Book ID
121501410
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
477 KB
Volume
104
Category
Article
ISSN
0002-7863

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Steric and electronic effects of substit
✍ David W. Allen; Phillip Heatley; Barrie G. Hutley; Malcolm T.J. Mellor πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 170 KB

The Wittig reaction between a phosphonium salt and a carbonyl compound in the presence of alkoxide ion in protic solvents may occur by two competing mechanistic courses (see Scheme).