𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Unusual retention of isoxazole ring under the influence of 3-(substituted nitrophenyl)-2-isoxazoline during catalytic hydrogenation of isoxazoline-substituted isoxazole systems

✍ Scribed by Vijay Singh; Samiran Hutait; Gaya P. Yadav; Prakas R. Maulik; Sanjay Batra

Publisher
Journal of Heterocyclic Chemistry
Year
2009
Tongue
English
Weight
233 KB
Volume
46
Category
Article
ISSN
0022-152X

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

magnified image

The cleavage of the isoxazole ring during the Raney‐Ni‐promoted catalytic hydrogenation is prevented under the influence of 3‐(substituted nitrophenyl)‐2‐isoxazoline in isoxazoline‐substituted isoxazole systems produced via 1,3‐dipolar cycloaddition either on the Baylis–Hillman derivatives or Grignard products. Unexpectedly, the hydrogenations in these diastereomeric compounds were observed to exclusively yield products, wherein the methoxycarbonyl and the hydroxyl or the acetyl groups exist syn to each other. J. Heterocyclic Chem., (2009).

📜 SIMILAR VOLUMES

ChemInform Abstract: Unusual Retention o
ChemInform Abstract: Unusual Retention of Isoxazole Ring under the Influence of 3-(Substituted nitrophenyl)-2-isoxazoline During Catalytic Hydrogenation of Isoxazoline-Substituted Isoxazole Systems.
✍ Vijay Singh; Samiran Hutait; Gaya P. Yadav; Prakas R. Maulik; Sanjay Batra 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 35 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v