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Unusual Reactivity of Dimethylsulfoxonium Methylide with Esters

✍ Scribed by Antonella Leggio; Rosaria De Marco; Francesca Perri; Mariagiovanna Spinella; Angelo Liguori

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
263 KB
Volume
2012
Category
Article
ISSN
1434-193X

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Reaction of Boranes with TMS Diazomethan
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✍ Jie Bai; Kenneth J. Shea πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 144 KB

## Abstract **Summary:** Borane reacts with TDM by a sequence of insertion and disproportionation reactions to yield tris‐(trimethylsilylmethyl)borane. No further addition of TDM occurs. Triallylborane and tris‐(4‐methoxyphenylethyl)borane initiate the copolymerization of TDM and dimethylsulfoxoniu