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Unusual reaction of trifluoroacetone with benzenesulfenyl chloride

✍ Scribed by N. M. Karimova; A. F. Kolomiets; A. V. Fokin

Book ID
105595697
Publisher
Springer
Year
1997
Tongue
English
Weight
73 KB
Volume
46
Category
Article
ISSN
1573-9171

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## Abstract Reaction of syn‐9,9′‐bibenzonorbornenylidene **(1a)** with benzeneselenyl chloride produced vic‐dichloride **(4)** exclusively, which corresponds to the cis‐addition product of **1a** with molecular chlorine, with retention of the original alkene configuration. Moreover, the reaction of