Unusual reaction of chloroacetyl chloride with 1,2-dichloroethene. Synthesis and properties of 2-chlorovinyl dichloromethyl ketone
✍ Scribed by G. V. Bozhenkov; V. A. Savosik; E. V. Rudyakova; Kha Kuok Khan’; A. I. Albanov; L. V. Klyba; A. N. Mirskova; G. G. Levkovskaya
- Book ID
- 111464876
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2008
- Tongue
- English
- Weight
- 224 KB
- Volume
- 44
- Category
- Article
- ISSN
- 1070-4280
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Kinetic studies on reactions of ozone with trans-1,2-dichloroethene (DCE) and vinyl chloride (VC) were performed in air. In the presence of scavengers of radicals, such as CHBCHO, the rates for both reactions are second order (first order in each reactant). Observed rate constants are (1.80 f 0.29)
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