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Unusual phosphorus basicity of 2,8.9-trioxa-1-phospha-5-azabicyclo[3.3.3]undecane and the molecular structure of 1-borano-2,8,9-trioxa-1-phospha-5-azabicyclo[3.3.3]undecane

โœ Scribed by Clardy, J. C.; Milbrath, D. S.; Verkade, J. G.


Book ID
126133119
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
424 KB
Volume
16
Category
Article
ISSN
0020-1669

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Nuclear magnetic resonance study of sele
โœ Jon M. Bellama; J. Dirk Nies; Nava Ben-Zvi ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 690 KB

The 'H, I3C and =Si nuclear magnetic resonance spectra of the parent compound and twelve derivatives of 2,8,9-trioxa-5-aza-l-silatri~yclo[3.3.3.O~~~]undecane (silatrane) are discussed. Effective Taft polarity constants for the silatrane snbstituents are proposed. An equation is developed to correlat