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Unusual michael reaction of 3-(4-Chlorophenyl)-1-phenylprop-2-en-1-one with 3-amino-N-phenyl-3-thioxopropanamide

✍ Scribed by V. D. Dyachenko, D. A. Krasnikov

Book ID
115451653
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
229 KB
Volume
48
Category
Article
ISSN
1070-4280

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📜 SIMILAR VOLUMES

1-(4-Hydro­xy­phenyl)-3-phenyl­prop-2-en
1-(4-Hydro­xy­phenyl)-3-phenyl­prop-2-en-1-one
✍ Parthasarathi, V. ;Praveen, V. N. ;Thamotharan, S. ;Vijayalakshmi, L. ;Bhaskar, 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 145 KB

In the title molecule, C 15 H 12 O 2 , the carbonyl group is in an s-cis conformation. The dihedral angle between the planes of the 4-hydroxyphenyl group and the phenyl ring is 34.96 (10) . Electron conjugation is observed between the central ÐCH CHÐC( O)Ð group and the attached rings. The crystal s

(2E)-1-{4-[(1E)-Benzylideneamino]phenyl}
(2E)-1-{4-[(1E)-Benzylideneamino]phenyl}-3-phenylprop-2-en-1-one
✍ Harrison, William T. A. ;Ravindra, H. J. ;Kumar, M. R. Suresh ;Dharmaprakash, S. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 518 KB

In the title compound, C 22 H 17 NO, the dihedral angles between the central benzene ring and the two terminal phenyl rings are 48.20 (4) and 49.62 (4) , resulting in a substantially twisted molecular conformation. Weak C-HÁ Á Á interactions help to consolidate the centrosymmetric crystal packing.

(2E)-1-(4-Chloro­phen­yl)-3-[4-(methyl­s
(2E)-1-(4-Chloro­phen­yl)-3-[4-(methyl­sulfan­yl)phen­yl]prop-2-en-1-one
✍ Harrison, William T. A. ;Yathirajan, H. S. ;Narayana, B. ;Mithun, A. ;Sarojini, 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

The geometrical parameters for the title compound, C 16 H 13 ClOS, are normal. The dihedral angle between the two benzene rings is 48.16 (5) . The non-centrosymmetric crystal packing is consistent with the substantial non-zero second harmonic generation response.