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Unusual Manganese(III)-Mediated Oxidative Free Radical Additions of 1,3-Dicarbonyl Compounds to Benzonorbornadiene and 7-Heterobenzonorbornadienes: Mechanistic Studies

✍ Scribed by Çalışkan, Raşit; Ali, Mohamed Fadelalla; Şahin, Ertan; Watson, William H.; Balci, Metin


Book ID
123606133
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
213 KB
Volume
72
Category
Article
ISSN
0022-3263

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Manganese(III) Acetate Catalyzed Oxidati
✍ Esra Findik; Mustafa Ceylan 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 German ⚖ 222 KB

## Abstract Manganese(III) acetate catalyzed oxidative radical‐addition reactions of __α__‐dicarbonyl compounds such as methyl acetoacetate (**6**), acetylacetone (**7**), and dimedone (**8**) to the mixture of 1‐ and 2‐phenylcyclohepta‐1,3,5‐triene (**4** and **5**) were investigated (__Scheme 1__