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Unusual Homocoupling in the Reaction of Diorganocuprates with an Allylic Halide

✍ Scribed by Norinder, Jakob; Bäckvall, Jan-E.; Yoshikai, Naohiko; Nakamura, Eiichi

Book ID
121276370
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
292 KB
Volume
25
Category
Article
ISSN
0276-7333

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It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l