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Unusual Fluorenylidene-philic Interactions for Effective Conformational Induction

✍ Scribed by Young-A. Lee; Ok-Sang Jung

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 132 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20011015)40:20<3868::aid-anie3868>3.0.co;2-o

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✦ Synopsis

Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [Pt (fm)] to give [Pt (X)(X')(fm)] (fm=9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X' ligands, OOCCH >OCH >OH.

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